get index of DataTable column with name
You can use DataColumn.Ordinal to get the index of the column in the DataTable. So if you need the next column as mentioned use Column.Ordinal + 1:
row[row.Table.Columns["ColumnName"].Ordinal + 1] = someOtherValue;
You can simply use DataColumnCollection.IndexOf
So that you can get the index of the required column by name then use it with your row:
row[dt.Columns.IndexOf("ColumnName")] = columnValue;