C vs C++ struct alignment

Both the C and C++ language standards make no requirements of struct padding and leave it to be a compiler implementation detail. A strict interpretation of this would mean that there is no guarantee a struct would be the same between the two.

In practice, however, a given version of a toolchain capable of both C and C++ (such as GCC or Clang) can pack an identical struct in the same manner, if needed. Without this, a lot of production code in the world simply wouldn't work. This is a guarantee given by the toolchain, however, and not the language.

It is worth noting that if you were to declare a similar struct to the C original, but added access specifiers (private, public and protected), that the layout would change, but that's a bit of a stretch since the struct is no longer identical.

This was most obviously wrong (on the interviewer side). It is clear to see that struct packing is the same for C and C++ for anybody who worked with any low-level API dealing with structs - for instance, a network API. All those are C functions, which accept 'C' structs, yet they are safely called millions of millions times a single day from C++ code.

You should be lucky you had this question. It makes it clear you should not be working there.

When C++ was developed, the developers figured out that C programmers relied on some things that the C++ developers didn't want to guarantee, but not guaranteeing them would mean that a lot of C code that was also valid C++ code would be broken when used as C++ code. Not desirable.

That's why they invented "POD" structures: A struct that didn't use any C++ features would behave in a C++ program exactly as it would in a C program (apart from the fact that implementation defined behaviour could change, since a C compiler and a C++ compiler are clearly not the same implementation. On the other hand, the C++ compiler would probably just copy the implementation definition from the C compiler).

If you take any plain C struct that is also a valid C++ struct (no members named "class", for example), and then you just add "public:" just after the opening brace, then its layout, order of members, alignment and so on can all change. Even though all struct members are by default public, so nothing really changed. Except that because of the "public:" it's not a POD anymore.