Is the order of writes to separate members of a volatile struct guaranteed to be preserved?

c

They will not be reordered.

C17 6.5.2.3(3) says:

A postfix expression followed by the . operator and an identifier designates a member of a structureor union object. The value is that of the named member, 97) and is an lvalue if the first expression isan lvalue. If the first expression has qualified type, the result has the so-qualified version of the typeof the designated member.

Since data has volatile-qualified type, so do data.bar and data.foo. Thus you are performing two assignments to volatile int objects. And by 6.7.3 footnote 136,

Actions on objects so declared [as volatile] shall not be “optimized out” byan implementation or reordered except as permitted by the rules for evaluating expressions.

A more subtle question is whether the compiler could assign them both with a single instruction, e.g., if they are contiguous 32-bit values, could it use a 64-bit store to set both? I would think not, and at least GCC and Clang don't attempt to.

If you want to use this in multiple threads, there is one significant gotcha.

While the compiler will not reorder the writes to volatile variables (as described in the answer by Nate Eldredge), there is one more point where write reordering can occur, and that is the CPU itself. This depends on the CPU architecture, and a few examples follow:

Intel 64

See Intel® 64 Architecture Memory Ordering White Paper.

While the store instructions themselves are not reordered (2.2):

2. Stores are not reordered with other stores.

They may be visible to different CPUs in a different order (2.4):

Intel 64 memory ordering allows stores by two processors to be seen in different orders bythose two processors

AMD 64

AMD 64 (which is the common x64) has similar behaviour in the specification:

Generally, out-of-order writes are not allowed. Write instructions executed out of order cannot commit (write) their result to memory until all previous instructions have completed in program order. The processor can, however, hold the result of an out-of-order write instruction in a private buffer (not visible to software) until that result can be committed to memory.

PowerPC

I remember having to be careful about this on Xbox 360 which used a PowerPC CPU:

While the Xbox 360 CPU does not reorder instructions, it does rearrange write operations, which complete after the instructions themselves. This rearranging of writes is specifically allowed by the PowerPC memory model

To avoid CPU reordering in a portable way you need to use memory fences like C++11 std::atomic_thread_fence or C11 atomic_thread_fence. Without them, the order of writes as seen from another thread may be different.

See also C++11 introduced a standardized memory model. What does it mean? And how is it going to affect C++ programming?

This is also noted in the Wikipedia Memory barrier article:

Moreover, it is not guaranteed that volatile reads and writes will be seen in the same order by other processors or cores due to caching, cache coherence protocol and relaxed memory ordering, meaning volatile variables alone may not even work as inter-thread flags or mutexes.