Memory position of elements in C/C++ union

In 6.7.2.1p16 the C standard guarantees that:

The size of a union is sufficient to contain the largest of its members. The value of at most one of the members can be stored in a union object at any time. A pointer to a union object, suitably converted, points to each of its members (or if a member is a bit- field, then to the unit in which it resides), and vice versa.

So, yes, you can rely on all members starting at the unions address (note this is the same for the first member of a struct).

The C++ standard includes a similar sentence with respect to C-style (i.e. only C-style members) unions/structs, because C++ allows to pass unions to C functions which does require this layout.The relevant section in the C++ standard is 9.5.

However, note there might be padding bits inside standard simple types (integers, floats). And their internal may vary (endianess). You also might violate strict aliasing rule (C: effective type).

From my experience, I would say 'yes', though I've checked the C++14 standard and it even guarantees this. (c++11 will most likely have the same effects) Chapter 9.5 states: All non-static data members of a union object have the same address

So, you can depend on this behavior.