In your Dockerfile: ADD fileA fileB. That will rename fileA to fileB at the moment of image creation.
ADD fileA fileB
fileA
fileB
You can split your command in 2 commands :
cp /usr/local/tomcat/webapps/app.war /usr/local/tomcat/webapps/client1.warrm /usr/local/tomcat/webapps/app.war
you can edit file inside container and commit changes without buiding image.
docker commit existing_containername commited_image_name
then run container with new for example
docker run --name tomcat -td commited_image_name