Qualify the * with the name of the table:
select rownum, table.* from table
Dave's answer is great, i'd just like to add that it's also possible to do that by placing the wildcard as the first column:
select *,rownum from table
Works, but the following won't:
select rownum,* from table
I've tested on MySQL.
Dave's answer did not work for me on Oracle 11g (table.* without alias). The following worked:
select rownum, t.* from table t