Try range(100,-1,-1), the 3rd argument being the increment to use (documented here).
range(100,-1,-1)
("range" options, start, stop, step are documented here)
In my opinion, this is the most readable:
for i in reversed(xrange(101)): print i,
for i in range(100, -1, -1)
and some slightly longer (and slower) solution:
for i in reversed(range(101))for i in range(101)[::-1]